Zur Koordination Mehrfunktioneller Thioether in Cyclopentadienyleisen-Komplexen

Article abstract of DOI:10.1016/0022-328X(86)80414-4

⁺ reacts with the ligands L-L and L-L-L to give the cations ⁺ (L-L= RS(CH2)_nSR, 1,4-dithiane) and ⁺ (L-L-L= 1,3,5-trithiane, tris(methylmercapto)methane) containing monodentate coordinated sulfur ligands.In a similar way, sulfur ligand bridged dinuclear dications <(C5H5Fe(CO)2)2(μ-L-L)>²⁺ and <(C5H5Fe(CO)2(μ-L-L-L)>²⁺ and trinuclear trications <(C5H5Fe(CO)2)3(μ-L-L-L)>³⁺ are formed.Irradiation of the mononuclear cations gives the chelate complexes 2-L-L)>⁺.