Journal of the Chemical Society. Perkin transactions II p. 211 - 214 (1986)
Update date:2022-08-30
Topics:
Liu, Michael T. H.
Tencer, Michal
Stevens, Ian D. R.
Kinetic data for the thermal decomposition of 3-phenyl-3-trifluoromethyldiazirine, 1-phenyl-2,2,2-trifluorodiazoethane, and 3-methyl-3-vinyldiazirine are reported.Detailed analysis of the previously studied diazirine decompositions suggest a mechanism in which a carbene-nitrogen complex is formed as the first intermediate.This complex, depending on the relative rates and stabilities of intermediates and products, may collapse to a diazo compound and /or form a free carbene.Thus for different diazirines the isomerization to a diazo compound may or may not be observed.
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