Journal of the Chemical Society. Perkin transactions II p. 1269 - 1274 (1983)
Update date:2022-08-30
Topics:
Lemmetyinen, Helge J.
Nucleophilic photocyanation of the unsubstituted aromatic hydrocarbons, naphthalene, biphenyl, and phenanthrene, in both dry and aqueous acetonitrile can be described by a mechanism involving two photoinduced transients.The primary step of the mechanism is the formation of a transient ionic complex through triplet excimer of aromatic hydrocarbon or, when an electron acceptor is present, through triplet exciplex.The attack of cyanide ion on the transient complex yields the cyanated radical, ArHCN., which in aqueous acetonitrile reacts with itself to yield cyano- and dihydrocyano-products or, in dry acetonitrile after being attacked by an electron, is oxidized to the cyano-product.The rate constants for the formation of radical ions and the attack of cyanide ion are calculated from the experimental results.
View MoreJinan Yijialian Economic and Trade Development Co., Ltd.
Contact:+86 0531-66729596
Address:jinan
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD
Contact:+86-571-88932183
Address:Hangzhou
Xinjiang Zhongtai Chemical Co., Ltd.
Contact:+86-991-8788172
Address:NO.78 XISHAN RD.URUMQI，CHINA
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Hubei Lingsheng Pharmaceuticals Co., Ltd.
Contact:+86-0710-3538058
Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Doi:10.1016/S0040-4020(01)01127-9
(2002)Doi:10.1016/0009-2614(94)00279-7
(1994)Doi:10.1007/s13738-017-1199-5
(2017)Doi:10.1002/hlca.19660490208
(1966)Doi:10.1002/anie.200601991
(2006)Doi:10.1016/j.ejphar.2018.01.042
(2018)
