Formation of Bicyclic Azepines by Intramolecular Trapping of Didehydroazepines

DOI: 10.1039/c39950001255

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1255 - 1256 (1995)

Update date:2022-08-11

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Authors:

Murata, Shigeru

Miwa, Masaki

Tomioka, Hideo

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Article abstract of DOI:10.1039/c39950001255

Photolysis of 2-(3-aminopropyl)phenyl azides 6 gives 2,3,4,4a-tetrahydro-1H-pyrido<2,3-b>azepines 7 in good yields, which are formed by intramolecular trapping of the ring-expanded didehydroazepine intermediate with an amino group.

Full text of DOI:10.1039/c39950001255

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