Journal of Organic Chemistry p. 1011 - 1014 (1980)
Update date:2022-08-11
Topics:
Bartsch, Richard A.
Juri, Pedro N.
A kinetic technique is utilized to determine the relative complexing abilities of 40 macrocyclic multidentate compounds for p-tert-butylbenzenediazonium tetrafluoroborate in 1,2-dichloroethane.The influence of ligand structure variations, such as ring size, nature of heteroatoms, and substituent effects, upon complexation efficiency is assessed.Maximum complexation is achieved with a 21-membered polyether macrocycle.
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