Synthesis and Diels-Alder reactions of enantiopure (-)-trans-benzo[d]-dithuene-S,S′-dioxide

DOI: 10.1016/0957-4166(96)00008-0

Source and publish data:

Tetrahedron Asymmetry p. 369 - 372 (1996)

Update date:2022-08-18

Topics:

Authors:

Cecchet, Elisa

Di Furia, Fulvio

Licini, Giulia

Modena, Giorgio

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Article abstract of DOI:10.1016/0957-4166(96)00008-0

Enantiopure (-)-trans-benzo[d]dithiine-S,S′-dioxide 4 was obtained by enantioselective oxidation of the parent benzo[d]dithiine. The reaction of the bis-sulfoxide with a series of cyclic dienes affords the corresponding Diels-Alder cycloadducts with diastereoselectivities ranging from fair to high and good chemical yields.

Full text of DOI:10.1016/0957-4166(96)00008-0

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