Bulletin of the Chemical Society of Japan p. 1973 - 1974 (1982)
Update date:2022-08-17
Topics:
Yoshida, Hiroshi
Nakajima, Mikito
Ogata, Tsuyoshi
Matsumoto, Kiyoshi
On treatment with a mixture of thiocarboxylic acid and perchloric acid in acetic anhydride, cyclopropenone gave acylthiocyclopropenium perchlorate in a good yield.Bis(acylthio)cyclopropene also yielded the salt under similar reaction conditions.The salt was stable under nitrogen at low temperatures, but was easily hydrolyzed to yield the corresponding cyclopropenethione.
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