Organic Letters p. 4087 - 4089 (2001)
Update date:2022-08-03
Topics: Regioselectivity Stereochemistry PHOTOCHEMICAL REACTION Photolysis Density functional theory (DFT) Cycloaddition Spectroscopic Characterization Quantum Yield UV Irradiation Radical mechanism Mechanistic study Rearrangement Reaction Chromophore Excited state
Campos, Pedro J.
Soldevilla, Alberto
Sampedro, Diego
Rodriguez, Miguel A.
matrix presented A novel aza-(vinylcyclopropane-cyclopentene) photochemical rearrangement is reported. 1-Pyrrolines are easily synthesized in good yields from N-cyclopropylimines. Hydrogen, alkyl, and aryl groups can be placed anywhere within the system, and the reaction proceeds regiospecifically.
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