
Journal of Organometallic Chemistry p. 231 - 239 (1992)
Update date:2022-08-11
Topics:
Jedlinski, Zbigniew
Misiolek, Andrzej
Jankowski, Andrzej
Janeczek, Henryk
Novel reactions of oxetane with K-/K+ and Na-/K+ complexes in which potassium cation is complexed by 18-crown-6 have been studied.Organometallic alkoxides formed by cleavage of an alkyl-oxygen bond in the oxetane molecule were used for one pot metallation of anisole and triphenylmethane.The reaction with carbon dioxide was also investigated.Reaction mechanisms have been studied by NMR, GLC-MS, IR techniques and chemical analysis.
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