Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 138 - 141 (1991)
Update date:2022-08-10
Topics:
Dorokhov, V. A.
Baryshnikova, T. K.
Gordeev, M. F.
Niyazymbetov, M. E.
Petrosyan, V. A.
A method was developed for preparation of alkyl-(2,2'-dipyridyl)amines, consisting of the reaction of alkyl halides with the N anion electrochemically generated from 2,2'-dipyridylamine.The alkylation occurs regiospecifically, and CH2Cl2 can also be used as the methylating agent.Complexes of alkyl-(2,2'-dipyridyl)amines with Pd(2+) and Cu(2+) salts were obtained.
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