Methylenation of esters with bis(iodozincio)methane-TiCl2-TMEDA system

DOI: 10.1246/cl.1999.825

Source and publish data:

Chemistry Letters p. 825 - 826 (1999)

Update date:2022-08-10

Topics:

Authors:

Matsubara, Seijiro

Ukai, Katsumi

Mizuno, Tsuyoshi

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1999.825

Methylenation of ester carbonyl group with bis(iodozincio)-methane was examined: a use of TiCl₂ and amine as mediators facilitated the reaction to give vinyl ethers in good yields.

Full text of DOI:10.1246/cl.1999.825

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