Journal of the American Chemical Society p. 4829 - 4832 (1984)
Update date:2022-08-17
Topics:
Matsumoto, Toshihiko
Yamamoto, Hiroki
Inoue, Shohei
In the self-condensation of formaldehyde catalyzed by thiazolium salts, dihydroxyacetone (triose), but not glycolaldehyde, was formed selectively and in high yield.This is of much interest as a facile and novel synthesis of triose from this C1 compound.A mechanism which can account for the selective formation of dihydroxyacetone is described.
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