Reaction of Amines with Haloalkanes. 5. Dissolution of Copper Activated by Sulfur in n-Butylamine-Carbon Tetrachloride Solutions

DOI: 10.1021/j100459a026

Source and publish data:

Journal of Physical Chemistry p. 2968 - 2972 (1980)

Update date:2022-08-11

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Authors:

Parodi, George A.

Miller, John G.

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Article abstract of DOI:10.1021/j100459a026

Earlier study has shown that oxygen causes the dissolution of copper metal in amine-haloalkane solutions.We have found that sulfur also activates copper metal for the dissolution process.A kinetic study has been made by using n-butylamine and CCl4 as reactants at 30 deg C.A mechanism involving an intermediate copper(I) sulfide film is proposed.

Full text of DOI:10.1021/j100459a026

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