Polymer p. 290 - 298 (2015)
Update date:2022-08-31
Topics:
Beyazkilic, Zeynep
Lligadas, Gerard
Ronda, Juan Carlos
Galià, Marina
Cádiz, Virginia
A series of novel aliphatic copolyesters bearing vinylsulfide and ketone functional groups were synthesized via lipase catalyzed polycondensation of vegetable oil derivatives. The vinylsulfide-containing hydroxyacid (VSHA) from 10-undecenoic fatty acid and the ketone-containing hydroxyester (KHE) from methyl oleate were used to obtain random copolymers and further sequential and single-step strategies involving the reactions with thiol and oxyamine were investigated. Good agreement between product and feed stoichiometries was achieved in both reactions for sequential modification, and the order of addition seems not to be a significant parameter. One pot functionalization allows for the single step modification, but not quantitative reactions were achieved.
View MoreTIANJIN FESTO CHEMICAL CO.,LTD
Contact:86-22-25814570
Address:No.12th,5th Ave.,TEDA,Tianjin,China
Rizhao Lanxing Chemical Indusrial Co.,Ltd
Contact:86-633-2616708
Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)
Contact:+86-512-69598882
Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Hangzhou Showland Technology Co., Ltd.
Contact:86-571-88920516
Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Contact:86-21-57725962
Address:shanghai
Doi:10.1166/jnn.2014.9237
(2014)Doi:10.1002/pol.1946.120010503
(1946)Doi:10.1002/anie.201808964
(2018)Doi:10.1016/j.bmcl.2013.01.115
(2013)Doi:10.1016/j.jorganchem.2010.04.024
(2010)Doi:10.1021/ja00014a027
(1991)