Journal of Physical Chemistry p. 2320 - 2323 (1984)
Update date:2022-08-11
Topics:
Merenyi, Gabor
Lind, Johan
Eriksen, Trygve E.
The kinetics of the redox reaction of one-electron-oxidized luminol with molecular oxygen has been studied with chemiluminescent techniques.The rate constants of the forward and reverse reactions have been determined to be 550 +/- 100 and (2.5 +/- 1.6)E9 M-1s-1, respectively.These values afforded the one-electron-reduction potential of 5-aminophthalazine-1,4-dione with E0 = 240 +/- 20 mV vs.NHE.
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