
Journal of the Chemical Society. Chemical communications p. 1301 - 1302 (1983)
Update date:2022-08-30
Topics:
Rooney, John J.
Silica-alumina catalyses the gas phase hydrogenation of norbornadiene and 1-chloroadamantane at the surprisingly moderate temperature of 90 deg C showing that when the carbonium ion intermediates are long-lived the R+ ...O- - surface species reacts with dihydrogen in a <2 + 2>-type reaction, and does so far more readily than the corresponding H+ ...O- - cation-anion pair.
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