Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2119 - 2128 (1987)
Update date:2022-08-16
Topics:
Kiennemann, Alain
Breault, Raymond
Hindermann, Jean-Paul
The selectivity of rhodium-based catalysts is very dependent on the choice of support or the promotors.Cerium oxide is very effective for ethanol promotion when added to Rh/SiO2 catalysts or used as support (70-80percent ethanol selectivity).The role of the cerium oxide has been studied by various techniques, namely chemical trapping, Fourier-transform ifrared spectroscopy and the use of probe molecules.The result show that when cerium oxide is added to rhodium catalysts, a new absorption band appears at 1725 cm-1 in the inrared spectra which may be attributed to a CO molecule bonded through both the carbon and oxygen atoms.Such an interaction could be responsible for the formation and stabilization of the formyl species which, from chemical trapping experiments, is proposed as a key intermediate.These results and those obtained with probe molecules would be in accordance with a reactional pathway where the formyl species is a building block of the C2-oxygenates and the acetaldehyde a primary product of the synthesis.In addition to its role in the activation of carbon monoxide towards hydrogenation, it is also shown that cerium oxide is responsible for the reduction of acetaldehyde to ethanol.
View MoreContact:+852 83038667
Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
jiangsu hualin chemical co.,ltd.
Contact:86-25-87787402
Address:jaingsu,china
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Jintan Jinnuo Chemical Co., Ltd.
Contact:+86-519-80199901
Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Contact:86-25-51817806
Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Doi:10.1016/S0040-4039(02)00493-8
(2002)Doi:10.1039/c4ra00791c
(2014)Doi:10.1021/ja00155a014
(1995)Doi:10.1016/j.tetlet.2013.11.078
(2014)Doi:10.1002/jlcr.3490
(2017)Doi:10.1021/jo01070a084
(1961)
