Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1447 - 1454 (1985)
Update date:2022-08-11
Topics:
Karpinski, Zbigniew
Juszczyk, Wojciech
Stachurski, Jaroslaw
The reactions of neopentane and n-butane in the presence of an excess of dihydrogen have been studied on films of Pd-Cu and Pd-Ag evaporated onto mica.The characterization of films showed that they were predominantly (111) oriented.The catalytic activity for isomerization of neopentane and n-butane was higher for ca. 10 atpercent Cu than for pure Pd, resembling the catalytic behaviour of Pd-Au(111) films.This does not, however, confirm the existence of the ligand effect in alkane isomerization over Pd-IB metal alloys.The catalytic activity of Pd-Ag(111) alloys decreases with increasing silver content, but on the basis of the inferred surface composition of these alloys this agrees with the conclusion drawn for the Pd-Cu system, i.e. the possible absence of the ligand effect.
View MoreContact:+86-535-8888888
Address:No.161 Haishi Rd.
MS( MAOSHENG )Chemical CO.,LTD
Contact:+86-519-82726678.82726378
Address:TAOXI INDUSTRY ZONE JINTAN
Jiaozuo Zhongwen Trading Coporation Limited
Contact:--
Address:East Renmin Road
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Contact:+(852) 301-98033
Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Doi:10.1002/adsc.200900608
(2010)Doi:10.1021/jo1007493
(2010)Doi:10.1002/chem.201100312
(2011)Doi:10.1246/bcsj.58.2443
(1985)Doi:10.1021/om500420d
(2014)Doi:10.1039/c8cc02185f
(2018)
