Journal of Physical Chemistry p. 5381 - 5386 (1983)
Update date:2022-08-11
Topics:
Borseth, Donald G.
Kuczkowski, Robert L.
The ground-state rotational spectra of 14 isotopic species of cyclopentene ozonide (6,7,8-trioxabicyclo<3.2.1>octane) were assigned.These included the normal isotopic species , all single-substituted deuterium, 13C , and 18O species, and all multiple-18O-substituted species.Three vibrational satellites of the normal isotopic species were also assigned.The dipole moment was found to be 2.48(1) D, with principal axis components /μa/ = 2.30(1) D, /μb/ = 0.0 D, and /μc/ = 0.91(1) D.The ground state of cyclopentene ozonide has Cs symmetry and the endo conformation.Its structure is discussed in relation to an ab initio molecular orbital calculation of the Cs conformer of ethylene ozonide.
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