DEDICATED CLUSTER
FULL PAPERS
Ayyamperumal Sakthivel et al.
at 59.627 MHz, with a (7.05 T) Bruker Avance 300 spectrome-
Catalytic Oxidations, (Ed.: B. Meunier), Structure and
Bonding, Heidelberg, Springer Verlag, 2000, Vol. 97.
[4] D. V. Deubel, G. Frenking, P. Gisdakis, W. A. Herrmann,
N. Rçsch, J. Sundermeyer, Acc. Chem. Res. 2004, 37, 645;
C. C. Rom a˜ o, F. E. Kꢀhn, W. A. Herrmann, Chem. Rev.
1
0
ter, with 5.5 ms H 90 pulses, 8 ms contact time, a spinning rate
1
3
of 5 kHz and 4 s recycle delays. C CP MAS NMR spectra were
1
0
recorded at 75.468 MHz with 2.8 ms H 90 pulses, 8 ms contact
time, a spinning rate of 8 kHz and 5 s recycle delays.
1
997, 97, 3197; W. A. Herrmann, F. E. Kꢀhn, Acc.
Chem. Res. 1997, 30, 169; G. Wahl, D. Kleinhenz, A.
Schorm, J. Sundermeyer, R. Stohwasser, C. Rummey,
G. Bringmann, C. Fickert, W. Kiefer, Chem. Eur. J.
Catalytic Reactions
The catalytic behaviour of the grafted samples (ca. 175 mg) was
tested by examining the oxidation of cyclooctene (0.8020 g;
1
999, 5, 3237; R. Poli, Chem. Eur. J. 2004, 10, 332.
[
5] M. Abrantes, A. M. Santos, J. Mink, F. E. Kꢀhn, C. C.
Rom a˜ o, Organometallics 2003, 22, 2112; F. Abugideiri,
R. Poli, in: Synthetic Methods of Organometallic and In-
organic Chemistry; (Ed.: W. A. Herrmann), Georg
Thieme: Stuttgart, 1997, Vol. 8, p. 103.
[6] F. Amor, P. Royo, T. P. Spaniol, J. Okuda, J. Organomet.
Chem. 2000, 604, 126; J. W. Faller, Y. Ma, Organometal-
lics, 1988, 7, 559; J. W. Faller, Y. Ma, J. Organomet.
Chem. 1989, 368, 45; J. Zhao, A. M. Santos, E. Herdt-
weck, F. E. Kꢀhn, J. Mol Catal. A: Chem. 2004, 222, 265.
8
mmol) at 328 K in a liquid-phase batch reactor with TBHP
(
5.5 M in n-decane; 16 mmol) as the oxidizing agent. A catalys-
t:oxidant:substrate ratio of 0.0063:2:1 was applied. The sam-
ples were analyzed every 30 min for 4 h and the reaction was
terminated after 24 h. The analyses were carried out using a
gas chromatograph (HP 5890) using an FID detector. The
yields and conversions were calculated according to calibration
2
curves (r ¼0.999) determined prior to reaction course.
[
7] A. Corma, H. Garcia, Chem. Rev. 2002, 102, 3837; D. E.
De Vos, M. Dams, B. F. Sels, P. A. Jacobs, Chem. Rev.
Acknowledgements
2
002, 102, 3615; N. E. Leadbeater, M. Marco, Chem.
A. S. is grateful to the Alexander von Humboldt-Foundation for
a postdoctoral research fellowship. J. Z. thanks the Deutscher
Akademischer Austauschdienst (DAAD) for a Ph.D. grant.
The authors thank Prof. Dr. R. Anwander, Prof. Dr. J. A. Lerch-
er and their co-workers and Dr. G. Raudaschl-Sieber for exper-
imental support.
Rev. 2002, 102, 3217.
8] C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli,
J. S. Beck, Nature 1992, 359, 710.
9] A. Sakthivel, P. Selvam, J. Catal. 2002, 211, 134; A. Sak-
thivel, S. E. Dapurkar, P. Selvam, Appl. Catal. A 2003,
[
[
2
46, 283; P. Selvam, S. K. Bhatia, C. Sonwane, Ind.
Eng. Chem. Res. 2001, 40, 3237; A. Sakthivel, P. Selvam,
Catal. Lett. 2002, 84, 37; A. Sakthivel, S. J. Huang, W. H.
Chen, L. Z. Huang, K. H. Chen, H. P. Lin, C. Y. Mou,
S. B. Liu, Adv. Functional. Mater. 2005, in press.
References
[
[
10] R. A. Sheldon, I. W. C. E. Arends, H. E. B. Lempers,
Collect. Czech. Chem. Commun. 1998, 63, 1724; R. A.
Sheldon, I. W. C. E. Arends, H. E. B. Lempers, Catal. To-
day 1998, 41, 387.
11] S. Leinonen, D. C. Sherrington, A. Sneddon, D.
McLoughlin, J. Corker, C. Canevali, F. Morazzoni, J.
Reedjik, S. P. D. Spratt, J. Catal. 1999, 183, 251; M. M.
Miller, D. C. Sherrington, J. Chem. Soc. Chem. Commun.
[
1] S. B. Kumar, M. Chaudhury, J. Chem. Soc. Dalton Trans.
1
991, 2169; P. Palanca, T. Picher, V. Sanz, P. G o´ mez-Ro-
mero, E. Llopis, A. Domenech, A. Cervilla, J. Chem. Soc.
Chem. Commun. 1990, 531; J. P. Wilshire, L. Leon, P.
Bosserman, D. T. Sawyer, J. Am. Chem. Soc. 1979, 101,
3
379; J. M. Berg, R. H. Holm, J. Am. Chem. Soc. 1985,
1
07, 925; J. P. Caradonna, E. W. Harlan, R. H. Holm, J.
Am. Chem. Soc. 1986, 108, 7856; f) F. J. Feher, K. Rahi-
mian, T. A. Budzichowski, J. W. Ziller, Organometallics
1
994, 55; M. M. Miller, D. C. Sherrington, S. Simpson, J.
Chem. Soc. Perkin Trans. 1994, 2, 2091; J. H. Aha, D. C.
Sherrington, Chem. Commun. 1996, 643.
1
995, 14, 3920; R. Clarke, M. Gahagan, R. K. Mackie,
D. F. Foster, D. J. Cole-Hamilton, M. Nicol, A. W. Mon-
tford, J. Chem. Soc. Dalton Trans. 1995, 1221; J. R. Back-
house, H. M. Lowe, E. Sinn, S. Suzuki, S. Woodward, J.
Chem. Soc. Dalton Trans. 1995, 1489; U. Piarulli, D. N.
Williams, C. Floriani, G. Gervasio, D. Viterbo, J. Chem.
Soc. Dalton Trans. 1995, 3329.
[
12] A. Stein, B. J. Melde, R. C. Schroden, Adv. Mater. 2000,
1
2, 1403; S. Teixeira, K. Dallmann, U. Schuchardt, R.
Buffon, J. Mol. Catal. A, Chem. 2002, 182, 167; R. Buf-
fon, U. Schuchard, J. Brazil. Chem. Soc. 2003, 14, 347;
G. Wang, G. Chen, R. L. Luck, Z. Q. Wang, Z. C. Mu,
D. G. Evans, X. Duan, Inorg. Chim. Acta 2004, 357, 3223;
[
[
2] J. Kollar, (Halcon Int.), US Patent 3,351,635, 1967; M. N.
Sheng, G. J. Zajaczek, (ARCO), GB Patent 1,136,923,
[13] J. Zhao, X. Zhou, A. M. Santos, E. Herdtweck, C. C. Ro-
m a˜ o, F. E. Kꢀhn, J. Chem. Soc. Dalton Trans. 2003, 3736;
F. E. Kꢀhn, M. Groarke, E. Bencze, E. Herdtweck, A.
Prazeres, A. M. Santos, M. J. Calhorda, C. C. Rom a˜ o,
I. S. GonÅalves, M. Pillinger, Chem. Eur. J. 2002, 8, 10;
F. E. Kꢀhn, W. M. Xue, A. Al-Ajlouni, A. M. Santos, S.
Zhang, C. C. Rom a˜ o, G. Eickerling, E. Herdtweck, In-
org. Chem. 2002, 41, 4468; A. Sakthivel, J. Zhao, M. Han-
zlik, F. E. Kꢀhn, Dalton Trans. 2004, 3338.
1
968.
3] R. A. Sheldon, Applied Homogeneous Catalysis with Or-
ganometallic Compounds, (Eds.: B. Cornils, W. A. Herr-
nd
mann) Wiley-VCH, Weinheim, 2 end., 2002, Vol. 1, p.
4
12; Transition Metals for Fine Chemicals and Organic
Synthesis, (Ed.: M. Beller, C. Bolm), Wiley-VCH, Wein-
heim, 1998, Vol. 2, p. 261; K. A. Jørgensen, Chem. Rev.
1
989, 89, 431; Metal-Oxo and Metal-Peroxo Species in
482
ꢂ 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
asc.wiley-vch.de
Adv. Synth. Catal. 2005, 347, 473–483