Journal of Organic Chemistry p. 3330 - 3333 (1985)
Update date:2022-08-11
Topics:
Kevill, Dennis N.
Anderson, Steven W.
The solvolysis of 2-adamantyl trifluoromethanesulfonate proceeds at a convenient rate at temperatures below ambient in a wide variety of pure and aqueous organic solvents and in ethanol-2,2,2-trifluoroethanol mixtures.A scale of Grunwald-Winstein Y values (YOTf) is developed for 26 solvents and it is found to much more closely resemble the corresponding yOClO3 scale than the corresponding scale of YOTs values.In aqueous ethanol, there is a preference for product formation by interaction with water molecules by a factor of ca. 1.5, essentially independent of solvent composition (96-50percent ethanol).
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