Journal of the Chemical Society. Chemical communications p. 788 - 789 (1980)
Update date:2022-08-04
Topics:
Maskill
Murray-Rust, Peter
Thompson, John T.
Wilson, Alan A.
The first secondary alkyl azoxyarenesulphonate 2-adamantyl azoxytosylate, has been made and shown to have the Z configuration about the nitrogen-nitrogen double bond, rates of solvolysis and activation parameters in aqueous ethanol, aqueous trifluoroethanol and aqueous hexafluoropropan-2-ol have been determined and a solvolytic mechanism involving unimolecular fragmentation and carbonium ion intermediates is proposed.
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Doi:10.1021/jm0601001
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