Organic Letters p. 2683 - 2685 (2009)
Update date:2022-08-11
Topics:
Millar, Jocelyn G.
Moreira, Jardel A.
McElfresh, J. Steven
Daane, Kent M.
Freund, Amy S.
The sex pheromone of the longtailed mealybug, identified as 2-(1,5,5-trimethylcyclopent-2-en-1-yl)ethyl acetate, represents the first example of a new monoterpenoid skeleton. A [2,3]-sigmatropic rearrangement was used in a key step during construction of the sterically congested tetraalkylcylopentene framework.
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