Journal of Fluorine Chemistry p. 421 - 424 (1987)
Update date:2022-08-11
Topics:
Eapen, K. C.
Tamborski, C.
The zinc coupling reaction of 1,2-dichloroiodotrifluoroethane (I) in acetic anhydride-methylene chloride has been reinvestigated in more detail than its original disclosure.The expected coupling product C4F6Cl4 was shown to be an isomeric mixture of three components, CF2ClCFClCFClCF2Cl (II, 80percent), CFCl2CF2CF2CFCl2 (IIa, 15percent) and CF2ClCFClCF2CFCl2 (IIb, 5percent).In addition, other products e.g.CF2-CFCl, C6F9Cl5 and C8F12Cl6 were formed in minor quantities.A probable mode of formation of various byproducts via initial formation of CF2-CFCl and subsequent telomerization is presented.
View More
Shandong Loyal Chemical industrial Co.,Ltd
Contact:0533-7451788
Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Shanghai He Yang International Trading Co., Ltd.
Contact:+86-21-52043598
Address:Room 816, Blag.5, No.58 Huachi Road
Kunshan Yalong Trading Co,.Ltd
Contact:86-512-57621185
Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Changzhou Sunsheng Chem Co., Ltd
Contact:+1-(989)-854-0648
Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Doi:10.1021/acs.joc.8b01182
(2018)Doi:10.1246/cl.2002.1138
(2002)Doi:10.1016/j.jcat.2008.01.029
(2008)Doi:10.1021/ja01142a011
(1952)Doi:10.1002/asia.201801784
(2019)Doi:10.1021/acsmedchemlett.0c00378
(2020)
