Approaches to Azepines: A New Azepine by the Photolysis of Dimethyl p-Azidosalicylate

DOI: 10.1021/jo00173a048

Source and publish data:

Journal of Organic Chemistry p. 5041 - 5043 (1983)

Update date:2022-08-29

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Authors:

Mustill, Reginald A.

Rees, Alun H.

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Article abstract of DOI:10.1021/jo00173a048

We have generated 3-methoxy-4-carbomethoxyphenylnitrene and 3,4-dimethoxyphenylnitrene under various conditions, in a search for new azepines.Unexpectedly, only the former, by photolysis of dimethyl p-azidosalicylate, gave an azepine.Intramolecular coordi

Full text of DOI:10.1021/jo00173a048

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