Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2205 - 2214 (1982)
Update date:2022-08-29
Topics:
Symons, Martyn C. R.
Albano, Emanuele
Slater, Trevor F.
Tomasi, Aldo
Electron spin resonance studies of tetrachloromethane after exposure to (60)Coγ-rays at 77 K reveal the formation of .CCl3 and CCl4.+ radicals.On warming in the presence of spin-traps, or on irradiating fluid solutions, nitroxide radical adducts have been detected that are characteristic of .CCl3 and chlorine atom adducts.In the light of this evidence and that of other investigators a mechanism for the radiolysis of tetrachloromethane is postulated.In the presence of oxygen, .CCl3 radicals are converted into Cl3COO. radicals.The use of spin-traps to detect these radicals is described and evaluated.
View MoreDaqing New Century Fine Chemical Co., Ltd.(expird)
Contact:010-57126694
Address:No.39, jinxing cun, honggang district
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Contact:86-21-31200601
Address:Room1618,FangzhengDaSha,No.1122 Xinjinqiao Road,Pudong New District,Shanghai ,China
Dezhou Longteng Chemical Co., Ltd.
website:http://www.sodium-methoxide.cn/
Contact:0086-18866052283
Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
HK Vast Medicinal Chemistry Int'l Group Limited(expird)
website:http://www.hkvast.com/
Contact:+86-15000309979
Address:NO.6,Lane 108,Qinzhou Road,Xuhui District,Shanghai
Doi:10.1002/zaac.200700061
(2007)Doi:10.1139/V10-130
(2010)Doi:10.1016/S0040-4020(97)10205-8
(1998)Doi:10.1016/S0022-328X(02)01397-9
(2002)Doi:10.1016/j.tetlet.2007.08.039
(2007)Doi:10.1515/bchm2.1974.355.1.617
(1974)
