Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2205 - 2214 (1982)
Update date:2022-08-29
Topics:
Symons, Martyn C. R.
Albano, Emanuele
Slater, Trevor F.
Tomasi, Aldo
Electron spin resonance studies of tetrachloromethane after exposure to (60)Coγ-rays at 77 K reveal the formation of .CCl3 and CCl4.+ radicals.On warming in the presence of spin-traps, or on irradiating fluid solutions, nitroxide radical adducts have been detected that are characteristic of .CCl3 and chlorine atom adducts.In the light of this evidence and that of other investigators a mechanism for the radiolysis of tetrachloromethane is postulated.In the presence of oxygen, .CCl3 radicals are converted into Cl3COO. radicals.The use of spin-traps to detect these radicals is described and evaluated.
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