Electron-transfer Reactions in Nitrogen Fixation. Part 1. The Electrosynthesis of Dinitrogen, Hydride, Isocyanide, and Carbonyl Complexes of Molybdenum: Intermediates, Mechanisms, and Energetics

DOI: 10.1039/DT9850001255

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1255 - 1264 (1985)

Update date:2022-08-11

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Authors:

Al-Salih, Talib I.

Pickett, Christopher J.

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Article abstract of DOI:10.1039/DT9850001255

Dinitrogen, hydride, carbonyl, and isocyanide complexes of Mo⁰ and W⁰ can be electrosynthesised from the molecular substrates N2, H2, etc. and precursors trans- (M=Mo; X=Cl, Br, I, SPh, or SBuⁿ; M=W;

Full text of DOI:10.1039/DT9850001255

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