A Formal CH Insertion Reaction of Aryl Nitrene into an Alkyl CH Bond. Implications for Photoaffinity Labelling.

DOI: 10.1016/S0040-4039(00)84102-7

Source and publish data:

Tetrahedron Letters p. 791 - 794 (1986)

Update date:2022-08-11

Topics:

Authors:

Torres, Mary Jennifer

Zayas, Jose

Platz, Matthew S.

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Article abstract of DOI:10.1016/S0040-4039(00)84102-7

Triplet m-nitrophenyl nitrene reacts with frozen polycrystalline toluene at the benzylic position to give appreciable yields of a formal CH insertion adduct.This reaction does not occur on photolysis of m-nitrophenyl azide in toluene solution.

Full text of DOI:10.1016/S0040-4039(00)84102-7

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