A Formal CH Insertion Reaction of Aryl Nitrene into an Alkyl CH Bond. Implications for Photoaffinity Labelling.

DOI: 10.1016/S0040-4039(00)84102-7

Source and publish data:

Tetrahedron Letters p. 791 - 794 (1986)

Update date:2022-08-11

Topics:

Authors:

Torres, Mary Jennifer

Zayas, Jose

Platz, Matthew S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84102-7

Triplet m-nitrophenyl nitrene reacts with frozen polycrystalline toluene at the benzylic position to give appreciable yields of a formal CH insertion adduct.This reaction does not occur on photolysis of m-nitrophenyl azide in toluene solution.

Full text of DOI:10.1016/S0040-4039(00)84102-7

Products guided by the article

Product name:BENZYL-(3-NITRO-PHENYL)-AMINE

Cas No:33334-94-0

R&D Labs maybe for 33334-94-0

Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Xi'an Terra Biochem Co. Ltd.

Contact:0086-29-88315623

Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075
SHANGHAI GILEADER ADVANCE MATERIAL TECHNOLOGY CO.,LTD

website:http://www.tanguitech.com/contact.asp

Contact:+86-021-58692556

Address:No.6 Building,No. 668 Hengan RD Pudong,Shanghai
Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China

Relevant to this article

Rapid production of nitrilase containing silica nanoparticles offers an effective and reusable biocatalyst for synthetic nitrile hydrolysis

Doi:10.1021/op9000065
(2009)
Fluorescence characterization of model compounds for cyanate monomers, cure intermediates, and cure product

Doi:10.1021/ma0215722
(2003)
A ¹³C and ¹⁵N Solid-State NMR Study of Structural Disorder and Aurophilic Bonding in Au^I and Au^III Cyanide Complexes

Doi:10.1021/ic8022198
(2009)
The Parallel between Phenyl-initiated C-C Coupling Reactions in Dirhodium Complexes and those Catalysed by Rhodium Particles

Doi:10.1039/c39950001089
(1995)
Pyridazine derivatives, VII. Synthesis and hypotensive activity of 3-hydrazinocycloalkyl[1,2-c]pyridazines and their derivatives.

Doi:10.1002/ardp.19893220602
(1989)
Color-Tunable Light-up Bioorthogonal Probes for In Vivo Two-Photon Fluorescence Imaging

Doi:10.1002/chem.201905183
(2020)

Article Doi