Journal of the Chemical Society. Chemical communications p. 1089 - 1091 (1995)
Update date:2022-08-11
Topics:
Wang, Zhi-Qiang
Long, Helen C.
Turner, Michael L.
Maitlis, Peter M.
Decomposition of <<(C5Me5)Rh(μ-CH2)>2(Ph)(CO)>+ (homogeneously, under CO) in solution gives PhCH=CH2, PhMe and C6H6, while phenyl (from PhI) reacts with surface methylene (from CO + H2) heterogeneously over rhodium metal to give PhEt, PhMe and C6H6; it is proposed that the two reactions are also related mechanistically.
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