Russian Chemical Bulletin p. 1970 - 1972 (1996)
Update date:2022-08-17
Topics:
Voronkov
Baryshok
Lazareva
The Si-C bond in 1-organylsilatranes is cleaved by bromine or iodine chloride to yield 1-bromo- or 1-chlorosilatrane respectively. In the presence of Et2O or THF and under the action of dioxane dibromide, 1-halosilatranes are formed together with 1-alkoxy- and 1-(ω-haloalkoxy)silatranes.
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