
Tetrahedron Letters p. 5265 - 5266 (1992)
Update date:2022-08-17
Topics:
Toro, Andras
Ambrus, Gabor
Title transformation involving catalytic epoxidation, Curtius rearrangement and acidic hydrolysis has been accomplished.This synthetic sequence offers a novel route from a partial microbial side chain degradation product of natural sterols into useful precursors of antiinflammatory, antiandrogen and gestagen pharmaceuticals.
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(1962)Doi:10.1021/om050325u
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(2017)