Journal of the Chemical Society, Dalton Transactions p. 1165 - 1166 (1991)
Update date:2022-08-11
Topics:
Suh, Myunghyun Paik
Kwak, Chee-Hun
Suh, Junghun
The kinetics of reduction of di-2-pyridyl ketone with NaBH4 leading to the formation of di-2-pyridylmethanol (dpm) was studied in the presence of Ni(II) or Cu(II).The metal ion-promoted reduction involved two successive intermediates.Based on the visible spectra and kinetic data concerning the intermediates, it is proposed that the first intermediate is (nickel(I) or copper(I) complex of the anion of dpm and that the second intermediate is the corresponding complex of dpm.
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