Bulletin of the Chemical Society of Japan p. 2040 - 2045 (1984)
Update date:2022-08-12
Topics:
Ishikawa
Arai
CO//2 TEA laser-induced photolysis of C//2H//5F was studied by using a time-resolved infrared fluorescence technique. Molecular elimination of vibrationally excited hydrogen fluoride (HF*) from C//2H//5F*** occurs in the process. Rotational temperatures and vibrational level populations of HF* are estimated from observed fluorescence spectra by computational fitting. Higher vibrational level are populated to a less extent in the decomposition under a collisionless condition. When the pressure of C//2H//5F is increased, however, population inversion is allowed among some levels. Possible reaction mechanism is discussed for the production of HF* at extraordinarily high vibrational levels.
View More
Contact:+49-9398-993127
Address:Untertorstr. 27
Beijing Mesochem Technology Co.,LTD
website:http://www.mesochem.com
Contact:0086-10-57862036
Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Contact:86 21 3772 9386
Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
shijiazhuang shuanglian chemical industry co.,ltd
Contact:0311-82190302
Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Shanghai birch chemical technology co.,ltd
Contact:+86-21-54096810
Address:No.2588,Jungong Road,Shanghai,China
Doi:10.1021/jm00144a032
(1981)Doi:10.1039/d0nj05296e
(2021)Doi:10.1039/c8tc02048e
(2018)Doi:10.1039/C39770000696
(1977)Doi:10.1021/jm00291a020
(1971)Doi:10.1021/acs.inorgchem.1c00663
(2021)
