Journal of Fluorine Chemistry p. 197 - 214 (1987)
Update date:2022-08-11
Topics:
Pola, J.
Chvatal, Z.
CW CO2 laser-photosensitized (SF6) oxidation of hexafluoropropene, chlorotrifluoroethene, 1,1-dichlorodifluoroethene, 1,2-dichlorodifluoroethene and hexafluoro-1,3-butadiene with molecular oxygen at total pressure 13-26.5 kPa leads with all but the last to the formation of carbonyl halides.The distribution of these products suggests that the oxidation occurs via a cleavage of intermediary dioxetanes.The reactivities of the olefins towards oxygen at mean effective temperature 710 K are nearly equal.
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