Journal of Fluorine Chemistry p. 67 - 74 (1980)
Update date:2022-08-11
Topics:
Fowler, Brian R.
Moss, Kenneth C.
Vanadium pentafluoride reacts via an oxygen exchange reaction with phosphorous oxytrifluoride to give VOF3 and PF5.The latter forms a weak 1:1 adduct.VF5 reacts with trifluoroacetic acid to form trifluoroacetyl fluoride and VOF3.Both reactions are indicative of the strength of the V=O bond and its influence on the course of the reactions of VF5 with oxygen containing materials.
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