Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3493 - 3498 (1982)
Update date:2022-08-29
Topics:
Voehringer, Cecilia M. de
Staricco, Eduardo H.
The reaction of C2F5 radicals with cyanogen chloride was studied between 293 and 573 K, using perfluoroethyl iodide as the free-radical source. The main product, C2F5Cl is formed via an addition reaction or by abstraction of a chlorine atom by C2F5.The reactions involved are C2F5+ClCN->C2F5Cl+CN (2) C2F5+ClCN->/<-C2F5ClCN (3) C2F5+ClCN->C2F5Cl+CN (4) C2F5+C2F5->C4F10 The Arrhenius plot shows pronounced curvature.The following rate constants were obtained for reactions (2) and (4)
Contact:86-27-84888681
Address:Wuhan economic & technology development zone
Shanxi Tongji Pharmaceuticals Co., Ltd.
Contact:+86-359-3024784
Address:Xikuang South Road, Ruicheng County , Shanxi
Jinan Decheng Hemu Medical Technology Co.，Ltd.
Contact:+86-531-68650525
Address:NO.554 Zhengfeng Road High-new Technology Development Zone
website:http://www.maisonchem.com.cn
Contact:0086-311-83833777
Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Contact:--
Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Doi:10.1134/S1070328410040032
(2010)Doi:10.3389/fmicb.2020.599911
(2020)Doi:10.1021/ja992719g
(1999)Doi:10.1016/j.tetasy.2016.01.015
(2016)Doi:10.1002/oms.1210170506
(1982)Doi:10.1139/v80-310
(1980)
