Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3493 - 3498 (1982)
Update date:2022-08-29
Topics:
Voehringer, Cecilia M. de
Staricco, Eduardo H.
The reaction of C2F5 radicals with cyanogen chloride was studied between 293 and 573 K, using perfluoroethyl iodide as the free-radical source. The main product, C2F5Cl is formed via an addition reaction or by abstraction of a chlorine atom by C2F5.The reactions involved are C2F5+ClCN->C2F5Cl+CN (2) C2F5+ClCN->/<-C2F5ClCN (3) C2F5+ClCN->C2F5Cl+CN (4) C2F5+C2F5->C4F10 The Arrhenius plot shows pronounced curvature.The following rate constants were obtained for reactions (2) and (4)
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