Journal of Fluorine Chemistry p. 189 - 192 (1994)
Update date:2022-08-17
Topics:
Hu, Chang-Ming
Chen, Jian
In the presence of catalytic amounts of stannous salts (20 molpercent) and aluminium powder, per(poly)fluoroalkyl iodides or bromides react smoothly with DMF under mild conditions to give the corresponding per(poly)fluoroalkyl aldehydes in good to excellent yield.A tin-containing intermediate was obtained.A possible mechanism is proposed.
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