
Tetrahedron Letters p. 5319 - 5322 (1981)
Update date:2022-08-17
Topics:
Minato, Akio
Tamao, Kohei
Hayashi, Tamio
Suzuki, Keizo
Kumuda, Makoto
1-Methyl-2-pyrrolyl-magnesium bromide and -zinc chloride, which were prepared from 1-methyl-2-pyrrolyllithium with MgBr2 and ZnCl2 respectively, reacted with aryl- and heteroaromatic halides to give the corresponding 2-substituted pyrroles in good to excellent yields in the presence of palladium-phosphine complexes as catalysts.
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(1972)