Synthesis by FVT and characterization of unhindered silanethiones

Article abstract of DOI:10.1080/10426509708545554

The retro-ene reaction of allylthio- and propargylthiosilanes led, under flash vacuum thermolysis (FVT) conditions, to unhindered silanethiones, characterized by their derivatives, and also directly by coupling of the FVT with gas-phase spectrometries. Monomeric silicon oxysulfide has been generated similarly. The unsubstituted silanethione was not obtained, but dehydrogenated into silicon monosulfide during FVT.

Full text of DOI:10.1080/10426509708545554

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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Synthesis by FVT and
Characterization of Unhindered
Silanethiones
Valerie Lefevre & Jean-Louis Ripoll
a
LCMT, ISMRA, Université de Caen , 14050 Caen, France
b
LCMT, ISMRA, Université de Caen , 14050 Caen, France
Published online: 17 Mar 2008.
To cite this article: Valerie Lefevre & Jean-Louis Ripoll (1997) Synthesis by FVT and
Characterization of Unhindered Silanethiones, Phosphorus, Sulfur, and Silicon and the
Related Elements, 120:1, 371-372, DOI: 10.1080/10426509708545554
To link to this article: http://dx.doi.org/10.1080/10426509708545554
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