
Synthesis p. 1090 - 1092 (1996)
Update date:2022-08-11
Topics:
Ramana
Potnis, Prashant V.
Cyclohexene-1-acetic acid (1) undergoes reaction with various aromatic substrates 2a-k in the presence of polyphosphoric acid (PPA) to give 1,2,3,4,4a,10a-hexahydrophenanthren-9(10H)-ones 3a-k by tandem acylation-cycloalkylation, which on dehydrogenation with Pd-C afforded the corresponding phenanthrenes 4a-k in high yields.
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Doi:10.1007/BF00960112
(1987)Doi:10.1021/ja500712z
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(2020)Doi:10.1039/b717068h
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(2013)Doi:10.1055/s-2005-869854
(2005)