Enantioselective synthesis of nagilactone F via vinylsilane-terminated cationic cyclization

DOI: 10.1016/S0040-4039(00)76743-8

Source and publish data:

Tetrahedron Letters p. 1503 - 1506 (1994)

Update date:2022-08-11

Topics:

Authors:

Burke, Steven D.

Kort, Michael E.

Strickland, Sharon M.S.

Organ, Helen M.

Silks III, Louis A.

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Article abstract of DOI:10.1016/S0040-4039(00)76743-8

An enantioselective total synthesis of nagilactone F is described. Functionalized tricyclic intermediate 3 was prepared using a high-yielding acetal-initiated/vinylsilane-terminated polyene cyclization of 5. Intramolecular alkoxy radical-mediated remote f

Full text of DOI:10.1016/S0040-4039(00)76743-8

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