Journal of Physical Chemistry p. 2402 - 2406 (1982)
Update date:2022-08-11
Topics:
Zhang, Fumin
Francisco, J. S.
Steinfeld, J. I.
The multiple infrared photon dissociation of CF3O radicals generated from bis(trifluoromethyl) peroxide has been investigated.Infrared fluorescence from HF<*>, formed by reaction of the liberated F atom with HI, was used to monitor the dissociation over a range of infrared fluences.A simple rate equation model has been used to interpret the multiphoton excitation and dissociation of the CF3O species.The kinetics of the recombination reaction, CF3O + F <*> CF3OF, have been investigated by scavenging the F atoms with added HI.The rate constant for this reaction at 300 K is determined to be (3.5+/-0.5)E10 L mol-1 s-1.
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