Tetrahedron Letters p. 5077 - 5080 (1989)
Update date:2022-08-29
Topics:
Naperstkow, Arvin M.
Macaulay, John B.
Newlands, Michael J.
Fallis, Alex G.
A series of <4+2> cycloadditions with 2,5-dimethylthiophene oxide (2), generated in situ by peracid oxidation of 2,5-dimethylthiophene (1), are described.In all cases the syn adduct (with respect to the sulfoxide oxygen) is formed exclusively.
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