Rearrangement of 1-Alkynylcyclopropanol to 3-Substituted 2-Cyclopentenone Promoted by a Catalytic Amount of Octacarbonyldicobalt-Triphenylphosphite

DOI: 10.1246/cl.1993.997

Source and publish data:

Chemistry Letters p. 997 - 1000 (1993)

Update date:2022-08-10

Topics:

Authors:

Iwasawa, Nobuharu

Matsuo, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1993.997

The rearrangement of 1-(1-alkynyl)cyclopropanols is catalyzed efficiently by the combined use of octacarbonyldicobalt and triphenylphosphite to give 3-substituted 2-cyclopentenones in high yields.

Full text of DOI:10.1246/cl.1993.997

Products guided by the article

Product name:3-Phenyl-2-cyclopenten-1-one

Cas No:3810-26-2

R&D Labs maybe for 3810-26-2

Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
xujianqiang

Contact:86-21-57725962

Address:shanghai
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Ring Specialty Chemicals Inc.

Contact:+1-416-493-6870

Address:Toronto, Canada
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China

Relevant to this article

Bis-phosphine monoxide platinum(II) and palladium(II) cationic complexes as Lewis acid catalysts in Diels-Alder and sulfoxidation reactions

Doi:10.1016/j.jorganchem.2006.05.022
(2006)
Doi:10.1021/ja01591a050
(1956)
The reactions of organoboranes with N-chloro-N-sodiocarbamates: A novel synthesis of N-alkylcarbamates

Doi:10.1016/S0040-4039(00)98045-6
(1990)
Directing the Rate-Enhancement for Hydronium Ion Catalyzed Dehydration via Organization of Alkanols in Nanoscopic Confinements

Doi:10.1002/anie.202009835
(2021)
Dimerization of 1-phenylcycloalkene cation radicals dependent on their structure

Doi:10.1021/ja950770o
(1996)
Doi:10.1051/ita:2000103
(1911)

Article Doi