Chemistry Letters p. 771 - 774 (1983)
Update date:2022-08-11
Topics:
Ishiyama, Jun-ichi
Senda, Yasuhisa
Imaizumi, Shin
The products of novel reductive cyclization, 1-adamantanol and 1-methyl-2-oxa-adamantane, were obtained in the hydrogenation of 7-methylenebicyclo<3.3.1>nonan-3-one over group VIII metal black catalysts in ethanol or cyclohexane. 1-Adamantanol was produced over Pd, Rh, Co and Ni catalysts, and 1-methyl-2-oxa-adamantane only over Co catalysts in cyclohexane.
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