Oxidation of didehydro-α-amino acids as a route to β-hydroxy-or β-amino-pyruvic derivatives and to α-acylglycinates

DOI: 10.1039/P19960001833

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1833 - 1837 (1996)

Update date:2022-08-12

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Authors:

Miossec, Benoit

Rudyk, Helene

Toupet, Loic

Danion-Bougot, Renee

Danion, Daniel

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Article abstract of DOI:10.1039/P19960001833

Oxidation of protected didehydro-α-amino acids with N-bromosuccinimide or lead tetraacetate affords imines of β-bromo- or β-acetoxy-pyruvates. The hydrolysis of brominated imines proceeds through addition of water followed by intramolecular displacement o

Full text of DOI:10.1039/P19960001833

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