ENANTIOSELECTIVE CATALYSIS. 54. HYDROGENATION OF METHYL ACETOACETATE USING NICKEL POWDER MODIFIED WITH NaBr/(R,R)-TARTARIC ACID

DOI: 10.1016/S0957-4166(00)82369-1

Source and publish data:

Tetrahedron Asymmetry p. 159 - 162 (1990)

Update date:2022-08-10

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Authors:

Brunner, Henri

Muschiol, Manfred

Wischert, Thomas

Wiehl, Juergen

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Article abstract of DOI:10.1016/S0957-4166(00)82369-1

Commercial Ni powder, activated with H2 and modified with NaBr/(R,R)-(+)-rartaric acid are heterogeneous catalysts for the enantioselective hydrogenation of methyl acetoacetate (MAA) to give (R)-(-)-methyl 3-hydroxybutanoate (MHB) in up 76.9percent ee.

Full text of DOI:10.1016/S0957-4166(00)82369-1

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