5,10,15,20-Tetrakis(2-amino-6-methoxycarbonylphenyl)porphyrin. Synthesis and Separation of Atropisomers Useful for Porphyrin Architecture

DOI: 10.1246/cl.1993.279

Source and publish data:

Chemistry Letters p. 279 - 282 (1993)

Update date:2022-08-29

Topics:

Authors:

Nishino, Norikazu

Sakamoto, Toshiaki

Kiyota, Hiroshi

Mihara, Hisakazu

Yanai, Tomoko

Fujimoto, Tsutomu

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Article abstract of DOI:10.1246/cl.1993.279

5,10,15,20-Tetrakis(2-amino-6-methoxycarbonylphenyl)porphyrin was synthesized and three atropisomers in four were successfully separated.Different from the related mono-substituted tetraphenylporphyrins (2-amino- and 2-methoxycarbonylphenylporphyrins), the rotation of the bond between phenyl and porphyrin rings was totally prohibited under thermal isomerization.

Full text of DOI:10.1246/cl.1993.279

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