
Chemistry Letters p. 279 - 282 (1993)
Update date:2022-08-29
Topics:
Nishino, Norikazu
Sakamoto, Toshiaki
Kiyota, Hiroshi
Mihara, Hisakazu
Yanai, Tomoko
Fujimoto, Tsutomu
5,10,15,20-Tetrakis(2-amino-6-methoxycarbonylphenyl)porphyrin was synthesized and three atropisomers in four were successfully separated.Different from the related mono-substituted tetraphenylporphyrins (2-amino- and 2-methoxycarbonylphenylporphyrins), the rotation of the bond between phenyl and porphyrin rings was totally prohibited under thermal isomerization.
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