Chemical Communications p. 11842 - 11845 (2016)
Update date:2022-08-11
Topics:
Ng, Chee Koon
Wu, Jie
Hor, T. S. Andy
Luo, He-Kuan
Binary catalyst systems comprising a cationic Ru-CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO2 utilizing pinacolborane at r.t. and 1 atm CO2, with the combination of [Ru(CNCBn)(CO)2(H)][PF6] and KOCO2tBu producing formoxyborane in 76% yield. A bicyclic catalytic mechanism was proposed and discussed.
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