Vinylic C-F bond activation with low-valent zirconocene: The generation and cross-coupling reactions of 1-fluorovinylzirconocene

DOI: 10.1016/S0040-4039(99)01491-4

Source and publish data:

Tetrahedron Letters p. 7261 - 7265 (1999)

Update date:2022-08-11

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Authors:

Fujiwara, Masaki

Ichikawa, Junji

Okauchi, Tatsuo

Minami, Toru

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Article abstract of DOI:10.1016/S0040-4039(99)01491-4

(p-2,2-Difluorovinyloxyphenyl)dimethylamine, readily obtained from 2,2,2-trifluoroethanol, is treated with zirconocene equivalent 'Cp₂Zr' to generate thermostable 1-fluorovinylzirconocene via a C-F bond cleavage. This 1-fluorovinylzirconocene c

Full text of DOI:10.1016/S0040-4039(99)01491-4

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